Pioneer at your own caution, are the words that come to me when I read this. The systems themselves are, in the end, designed for men's hand at use. it would be fair to reason you could use it seemingly anywhere, but just because there isn't much mention of using it outside it's set up grounds, does not mean you always can.
Intuition tells me that, like any language, it's purpose and power is meaningless without understanding the language and having it be a part of you. That would really be the first step. Understanding the language to the point where it is like a completely second language, full of it's own emotions for you.
After that, sigils, seals, the Key, I am sure there are other applications, but be wise with the voice of the angels. You do not want to foul your relationship with them. It's nasty business.